Organic Metallic Compounds

Making full use of the cylinder business experience gained through our work with fluorine gases, Central Glass is also working to develop non-fluorine products. We supply Hf, Zr, Ti, Si, Ta and other compounds as precursors for the MOCVD/ALD technique, and we exploit our proprietary purification and analytical technologies to the full to attain a high purity. In particular, we have developed a technique for removing Zr from Hf compounds which has been difficult to do as Zr and Hf are of the same family of elements.

Hafnium Precursors

Product Name State at room temperature Boiling point [°C] Purity CAS No. Applications
Hf[N(CH3)2]4
[TDMAH]
Solid (melting point is 28°C) 40°C/0.1Torr >99.999%* 19782-68-4 HfO2 ,HfAlON, HfSiON layer materials
Hf[N(CH3)(C2H5)]4
[TEMAH]
Liquid 62°C/0.1Torr 352535-01-4
Hf[N(C2H5)2]4
[TDEAH]
Liquid 84°C/0.1Torr 19824-55-6
Hf[Ot-(C4H9)]4
[HTTB]
Liquid 61°C/1Torr 2172-02-03

Notes

* Zr Excluding density

Standard Grade: Zr<100 wt.ppm

High Pure Grade: Zr<10 wt.ppm

Ultra High Pure Grade: Zr<1 wt.ppm

Other Precursors

Product Name State at room temperature Boiling point [°C] CAS No. Applications
Zr[N(C2H5)2]4
(TDEAZ)
Liquid 79°C/0.1Torr 13801-49-5 CVD High-kmaterial
Zr[N(CH3)(C2H5)]4
(TEMAZ)
Liquid 65°C/0.1Torr 175923-04-3
Si[N(CH3)2]3H
(3DMAS)
Liquid 33°C/1Torr 15112-89-7
Si[N(CH3)(C2H5)]3H
(3EMAS)
Liquid 25°C/0.2Torr 496864-53-0
Ti[N(CH3)2]4
(TDMAT)
Liquid 50 °C/0.5Torr 3275-24-9 CVD TiN layer material
Ti[N(CH3)(C2H5)]4
(TEMAT)
Liquid 80°C/0.1Torr 308103-54-0
Ti[N(C2H5)2]4
(TDEAT)
Liquid 112°C/0.1Torr 4419-47-0
Ge(CH3)3H
(3MGE)
Liquid 27°C 1449-63-4 Implantation material SiGe material
Ge(CH3)4
(4MGE)
Liquid 44°C 865-52-1

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